Virginia Tech chemistry Professor Harry Dorn has developed a new area
of fullerene chemistry that may be the backbone for development of
molecular semiconductors and quantum computing applications.
As part of the research to place gadolinium atoms inside the carbon
cage for MRI applications, Dorn created 80-atom carbon molecule with
two yttrium ions inside. Then he began to fool with the materials of
the cage itself. He replaced one of the 80 atoms of carbon with an atom
of nitrogen (providing Y2@C79N). This change leaves the nitrogen atom
with an extra electron. Dorn discovered that the extra electron,
instead of being on the nitrogen atom on the fullerene cage surface,
ducks inside between the yttrium ions, forming a one-electron bond.
"Basically, a very unusual one electron bond between two yttrium
atoms," he said.
"No one has done anything like this," said
Dorn. "Since the article was published, we now know that we can take
the electron back out of the fullerene cage."
He says the
discovery could be important to the new fields of spintronics,
molecular electronics, and micro to nanoscale electronics, as well as
the new field of quantum computing.
Read more here (EurekAlert)
Â